The nitty-gritty depends on the consular worker you encounter but then there is a different problem.
If you look at the application that needs to be submitted to the Consulate for a VISA there are 2 different forms:
Everyone except citizens of US, Great Britain, Canada, and Georgia
Citizens of US, Great Britain, Canada, and Georgia
You can take a look at consular service page. Given the length of the form he will be required to submit with his British Passport I would suggest that he renew his Australian passport and apply for Russian visa with it.
Sorry the portal is in Russian.
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